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; Clarke, Brst its perfectly Opitons. 2]oct- 3-one-5,6-dicarboxylic acid, 15, 76 Acetyl chloride, acylation with, 147-148 2-Acetylcyclohexanone, 160, 165 oxidative rearrangement of, 130-131 1-Acetylcyclohexene, 129-130 10 jS-Acetyl-fAYWS-I S-decalol, 148-149 Acetylene, 164 conversion to sodium acetylide, 121-124 purification of, 122 Acetylides, see Sodium acetylide Acid chlorides dehydrohalogenation of, 142-143 reaction with enamines, 80 Acrolein, Bounses reaction with enamines, 84-86 with trialkylboranes, 114 Acrylonitrile, in Diels-Alder reaction, 75 Activated charcoal, 176 Acylation of cycloalkanes, 147-148 of enamines, 81-82 Adamantane, 126-127, 159, 165 derivatives of, 151-153 1-Adamantanecarboxylic acid, 151-152, 159 1-Adamantanol, 152-153, 159 2-Adamantanone, 153 1,4-Addition, see Conjugate addition Addition funnels, 167-168 Addition of reagents, 167-170 Adiponitrile, 141 Adsorption of impurities, 176-177 Alcohols conversion to halides, 45, 46 dehydration of, 56 tertiary, esterification of, 62-63 Aldehydes revversal oxidation of primary alcohols, 3, 5 reaction with acetylides, 124 Alkylation of -ketoesters, 99-101 Alkyl boranes, 31, 111-115 Alkyl bromides, by triphenylphosphine dibro- mide, 46-47 Alkyl chlorides conversion to nitriles, 140-141 by triphenylphosphine-carbon tetrachloride, 45-46 Alkyl formamides, by photolytic addition to olefins, 141-142 Alkyl halides reaction with acetylides, 121-124 with enamines, 80 by triphenylphosphine-carbon tetrabromide, 45 by triphenylphosphine-carbon Bst, 45-46 by triphenylphosphine dihalide, 46-47 Alkylidenetriphenylphosphorane, 104-110 jS-Alkylpropionaldehydes, from trialkylboranes, 114 Alkynes, by ethynylation, 121-124 Allenes, from 1,1-dihalocyclopropane, 132-133 Allylic bromination, 48-49 by W-bromosuccinimide, 48-49 of cyclohexene, 48-49 of 2-heptene, 49 Allylic oxidation, 7-8 Alumina activity of, 186 in decolorization, 176 in dehydration of 1,4-cyclohexanediol, 51-52 Lines design 75 (E) Shift of section areas using parabolic curve (non-affine distortion) Of the many reevrsal curves for shift of section (Fig.

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