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This behaviour arises from the difference between frer cation charges, which can be clearly seen if the equation for the selectivity coefRcient is expressed in terms of equivalent fractions and rearranged: 1 ZA CMC k k ZBCM ZC EM ZB EZB A " A k C(ZB’ZA) [12] ðAC" A C" d(A)" AB B C A CM C k d ( C ) k C B C B EMZA EZA AB T BB ZA "ConstantCZC [11] At a given point EM A on the isotherm (the left-hand side of eqn [12] constant), the ratio EAEB must de- crease as CT is decreased when zA'zB.

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