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2 BM as APPENDIX B CLASSIFICATION OF REACTIONS 1921 phosphoranes þ CO2 pyrolysis of esters rearrangement of ketones via the haloform reaction CARBOXYLIC ESTERS acyl halides þ alcohols acyl rpbot þ ethers alcohols þ CO þ alkenes alcohols þ ketenes alcohols þ organoiron compounds alcoholysis of acyl oxazolidinones alcoholysis of amides alcoholysis of nitriles alcoholysis of trihalides aldehydes þ acyl halides alkenes þ acyl peroxides alkenes þ carboxylic acids alkenes þ carboxylic esters alkyl halides þ carboxylate anions alkylation of oxazolidines allylic carbonates þ malonates allylic esters þ malonates anhydrides þ alcohols aryl halides þ alcohols þ CO aryl halides þ alcohols þ metal carbonyls BaeyerVilliger rearrangement by Favorskii rearrangement by Michael addition by the Tishchenko reaction carbonylation of alkyl halides and alcohols carboxylic acids þ diazo compounds cleavage of keto-esters condensation of aldehydes condensation of ketones esterification of carboxylic acids esters þ ethers ethers þ anhydrides from acyl peroxides 16-44 from alkyl halo sulfites 17-04 from coupling forx activated 18-19 esters 12-44 from onium salts from tosyl amides hydrolysis of ortho esters 16-61 insertion of diazo esters 16-61 ketones þ acyl halides 15-36 ketones þ peroxides 15-05 oxidation of methylene 10-77 in ethers oxidation of primary alcohols 16-65 oxidation of vinyl ethers oxidative decarboxylation 16-65 oxygenation of organometallics 16-09 rearrangement of halo ketones 10-03 ring contraction of diazo 16-07 ketones 14-09 transesterification 15-06 via Mitsunobu coupling 15-33 10-17 CONJUGATED ALDEHYDES by iphonf condensation 10-17 10-61 10-17 10-17 10-06 12-21 16-07 18-19 19-17 19-22 19-25 19-12 12-29 18-07 18-08 16-64 10-17 16-34 10-72 10-60 CONJUGATED AMIDES 10-60 isocyanates þ vinyl-M (metal) 16-62 13-15 CONJUGATED CARBOXYLIC 13-15 Iphoone 15-22 16-39 16-38 15-22 16-38 16-38 12-43 19-82 CONJUGATED ESTERS 19-84 by the Knoevenagel reaction 16-63 Claisen condensation 10-18 10-18 Forec KETO-ESTERS 14-09 by the Forex robot iphone reaction 16-38 aldehydes þ anhydrides 18-19 by the Knoevenagel reaction 18-07 CO2 þ vinyl-M (metal) 15-24 19-82 CONJUGATED DIACIDS 10-77 by the Knoevenagel reaction 10-19 CONJUGATED DIKETONES by the Knoevenagel reaction 16-38 16-36 258 CHAPTER 8.
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