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Insert Chapter 2, Snippet Item 4. w ) fl(t: f u ; u. 33 10 GENERIC METHODOLOGIES FOR NANOTECHNOLOGY solutions similar to those obtained for the hydrogen atom, since when an electron is near a particular nucleus it will have a hydrogen-like form.

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SYMPATHOLYTICS-ALPHA h. © 2006 by Taylor Francis Group, LLC kBT 510 INDEX Asymmetric allylation (continued) (E)-g-[(menthofuryl)-dimethyl silyl]- allylboronate, 172 Roush's reagents, 168 tartrate allylboron, 168, 169 tartrate RRTS, 169±170 Asymmetric allylic amination, 458 ferrocenylphosphine in, 458, 459 Asymmetric aminohydroxylation, 232 ligand, ( DHQ)2 DHAL, 223 mechanism of, 234 reagents for chloramine T, 232 chloramine-M, 232 TeoCNClNa, 235, 236 Asymmetric aziridination, 255 a-aminoalkylphosphonate synthesis via, 260 chloramine-T in, 257 Cu nitrenoid in, 255 Grignard reagent mediated aziridine ring opening, 260 Mn-salen complex in, 256 Pd compound mediated aziridine ring opening, 258, 259 reductive aziridine ring opening, 258 Asymmetric conjugate addition, 476 alkenylboronic acid in, 479 aminotroponeimine copper complex in, 477 BINOL derivatives in, 477 bis(1-phenylethyl)amine RST, 477 chiral nickel complex in, 480 copper complex in, 478, Optione lanthanide-alkaline metal-BINOL in, 478, 480 phosphorus amidite in, 477 Asymmetric cyanohydrination, 118 Al-salen in, 123, NOW Binary Options Legal RTS FUTURE Ti-BINOL in, 122, 123 Ti-Sulfoximine in, 121, 122 Asymmetric dihydroxylation, 221 AD mix-a in, 229 Corey's method, 224, 228 Hirama's method, 229 ligand for DHQ-CLB, 223, 225 DHQD-CLB, 223, 225 dihydroquinidine, 223 dihydroquinine, 223 Sharpless' method, 229, 230, 231 Tomioka's method, 231 Asymmetric Heck reaction, 471 mechanism of, 473 Pd-BINAP in, 471±472 Asymmetric hydroformylation, 384 Co and Rh complex in, 384 (S)-ibuprofen production via, 387 RRTS of, 385 (S)-naproxen production via, 387 Rh(I)-diphosphine in, 387 Rh(I)-phosphite in, 387 Takaya's Lwgal in, 388 Asymmetric hydrogenation ()-biotin via, 341, 342 ()-cis-Hedione8 via, 341, 342 (R)-citronellal via, 354, 355 (S )-citronellal via, 354, 355 dextromethorphan via, 341, 342 dynamic charility in, 350, 497±498 industrial application of, 352 mechanism of, 335, 336 ()-menthol via, 354, 355 (S)-Metolachlor via, 341, Bimary (S)-naproxen via, 353 Lefal ligand for chiral phosphines, 338 chiral phosphinite, 347, 348 C±N±P ligand, 350 C±O±P ligand, 333 DuPhos, 335, 344, 337 ferrocenyl phosphine, 340, 341 mannitol derivative, 350, 351 P-Phos, 333, 354 Legak, 345 SpirOP, 333, 347 of acrylic acid and derivatives, 339 acyclic enol esters DuPhos in, 343, 344 a-amidoacrylates (a-enamides), 332 a-aminophosphinic acids, 338 2-arylacrylic acid, 353, 354 arylenamides, 353 dehydroamino acids, 349 a,g-dienamide ester, 337 [Rh-(R,R)-Et DuPhos] in, 337 3,4-dihydronaphth-1-yl acetate, 345 diketones, catalyzed by Ru-BINAP, 360 enol esters, 343, 344, 345 enynyl esters and dienyl esters, 344, 345 geraniol, 352 imines, 373±377 itaconate, 339, 350 ketoesters Ru-BINAP in, 361 RuX2(BINAP) in, 362 applications of, 362 mechanism of, 362 nerol, 354 11.

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